A Sensitive Search for Deuterated Water in Comet 8p/tuttle∗

We report a sensitive search for deuterated water (HDO) in comet 8P/Tuttle using high-resolution spectroscopy at infrared (IR) wavelengths. The deuterium enrichment of cometary water is one of the most important cosmogonic indicators in comets. The (D/H)H2O ratio preserves information about the conditions under which comet material formed, and tests the possible contribution of comets in delivering water for Earth’s oceans. Water (H2O) and HDO were sampled in comet 8P/Tuttle from 2008 January 27 to 2008 February 3 using the new IR spectrometer (Cryogenic Infrared Echelle Spectrograph) at the 8.2 m Antu telescope of the Very Large Telescope Observatory atop Cerro Paranal, Chile. Twenty-three lines of HDO were sampled near 3.7 μm, leading to a production rate of 4.73± 1.68× 1025 s−1. Combining this value with the H2O production rate of 5790± 250× 1025 s−1 provides a formal value of (D/H)H2O = 4.09± 1.45× 10−4 in comet 8P/Tuttle. This value is larger by a factor of 2.62± 0.93 than Vienna Standard Mean Ocean Water, and is comparable to enrichment factors measured for three other Oort cloud comets. The technique described here provides unprecedented sensitivities, ultimately permitting us to routinely measure this prime cosmogonic indicator, even in comets having relatively modest gas production rate like 8P/Tuttle.